The hydrogen atom model and the Rydberg constant
Problem Statement
The hydrogen atom model and the Rydberg constant
Problem Statement
In Bohr's atomic model, the energy states of electrons orbiting the electrodes or nucleus are discontinuous (quantized) and are specified using the quantum number n ($n=1, 2, 3, ...).
When a photon is shone onto an electron in a hydrogen atom in its ground state (n=1), the electron ionizes to the highest energy state (n=∞). If E∞ is the minimum energy required for ionization (ionization energy), then the ground state energy E1 is expressed as follows:
E1=−E∞Furthermore, the energy level En of a hydrogen atom in the state of quantum number n is expressed using the ground state energy E1 as follows:
En=n2E1Now, the electron of this hydrogen atom has transitioned from an excited state with quantum number n=4 to a state with quantum number n=2. Find the energy ΔE of the photon emitted as a result of this transition.
Constraints
- E∞=2.18×10−18 J
Input Format
When the calculated photon energy ΔE is expressed in units of J, the value can be expressed as A×10−23. Find the value of the coefficient A in this case and input the natural number obtained without rounding.
Solution
Explanation
Calculation of Energy Levels
From the problem statement, the energy level En of a hydrogen atom in a state with quantum number n can be rewritten using the ionization energy E∞ as follows:
En=−n2E∞When an electron transitions from the state n=4 to the state n=2, the energy levels E4 and E2 in each state are as follows:
E4=−42E∞=−16E∞ E2=−22E∞=−4E∞Energy of Emitted Photons
The energy of photons emitted with a change in energy level, ΔE, is equal to the energy difference before and after the transition.
ΔE=E4−E2 ΔE=(−16E∞)−(−4E∞) ΔE=(41−161)E∞=163E∞Numerical Substitution
Substitute the given constraint E∞=2.18×10−18 J into the constraint.
ΔE=163×2.18×10−18 ΔE=166.54×10−18 ΔE=0.40875×10−18 JWe transform this into the form A×10−23 specified in the input format.
ΔE=0.40875×103×10−23=408.75×10−23 JTherefore, the value of the coefficient A is 40875.